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        Carbon black, also called charcoal black lamp black, pigment black, soot or black carbon, is a fine particle carbon pigment obtained as soot from the incomplete combustion of many different types of organic materials, such as natural gas, or oil. Carbon black is usually a fine, soft, black
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powder.It is very stable and unaffected by light, acids and alkalis. It is commonly used in printing and lithograph inks and in Chinese ink sticks. In industry, carbon black is used as a filtration material and a filler /pigment in coatings, rubber, plastics, paints, carbon paper, and crayons.
      Some synonyms for carbon black pigment ---- Channel black; lampblack; Pigment Black 6 and 7; CI 77266; gas black; diamond black; smoke black; soot black; flame black; furnace black; acetylene black; thermal black; graphite; charcoal black; coal black; bone black; vine black; sumi (Jap.); hiilimusta (Fin.); nero di carbone (It.); noir de carbone (Fr.)
 
Carbon Blacks

  Carbon Blacks  
  Color Index Pigment Black 6, 7, 8
  Formula C (Carbon)


Structure
         Carbon blacks are manufactured by thermal oxidative dissociation of hydrocarbons such as mineral oils or natural gases. They consist of elemental carbon, but there is a wide variety of products available, dependent on the starting materials and method of manufacture.
        Carbon blacks are classified according to an internationally recognized system, which signifies the manufacturing process and the jetness. The first two letters designate the strength of the pigment; high color (HC), medium color (MC), regular color (RC), and low color (LC). The final letter describes the manufacturing process; furnace (F) and the channel/gas process (C) (for example: HCF = high color furnace).
        Channel blacks are produced by burning petroleum gases in an atmosphere deficient in oxygen. This process is not very used because it has disastrous consequences on the environment.
        Furnace blacks are produced by the thermal oxidative process: hydrocarbon oils are burned in a limited supply of air.

Properties

Properties of carbon blacks
Property Carbon Blacks
Light Fastness Excellent
Resistance to solvents Good
Chemical Stability Excellent
Heat Stability Excellent

Color
The particle size determines the intensity of blackness, known as jetness, smaller particles giving higher values.

Surface area
Carbon blacks differ by their surface area.

  Average surface area
  Channel blacks 110 m2/g
  Furnace blacks 80 m2/g
   
Problems

Absorption
        The light dusty form of carbon blacks allows them to be converted to an easy to disperse pellet form by the dry pelleting process. Over a period of time carbon blacks absorb active ingredients in a paint formulation, such as the metal soaps used as driers in air-drying alkyds. This absorption can lead to problems, however, doubling the dosing of drier content is a common way of compensating for this issue.

Flocculation
        Following dispersion small particles of carbon black have a tendency to flocculate. To minimize this tendency it is necessary to take utmost care when diluting paints. Only small calculated additions should be made with thorough homogenization between additions.

Dispersion
        Carbon blacks can be difficult to disperse as they have very small particles with a correspondingly large surface area. Improved dispersions can be attained by oxidizing the surface of the pigment or by adding small quantities of organic groups such as carboxylic acids. Such groups decrease the pH of the aqueous extract and aid the wetting of the particles.

Viscosity of the paint
        Particles of carbon form clusters which are often compared to a cluster of grapes, held together by forces ranging from weak physical attraction to chemical bonds. This structure affects the dispersibility, the jetness, gloss, and, above all, the viscosity of the paint.

Uses
         Carbon black is one of the oldest of pigments. It was used 27000 years ago for cave paintings, and in 2500 before Christ by the Egyptians in inks. It was also used for the printing process during the Middle Ages.
         The rubber industry is the biggest user of carbon blacks by a large margin, in comparison, the paint industry is only a modest user. The printing inks industry also uses significant quantities.
Finer particle blacks are used for high-quality finishes such as in automotive paints on account of their higher jetness. Medium size blacks are used for intermediate quality paints, whereas the coarser pigments are used for decorative paints.
        For tinting purposes coarser grades are usually used as their lower strength means they are easier to control.

Price
         The price of carbon blacks varies depending on particle size, increasing as the particle size is decreasing. However, carbon black is a relatively cheap pigment. Speciality grades, made for specific applications, are more expensive.

 
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